To determine the concentration of limewater Essay Example for Free

To determine the concentration of unslaked fluxing lime piss EssayThe look of my experiment is to find the concentration of lime weewee solution provided.To do this I am provided with the following chemicals.Limewater system 250cm (1g dm )Hydrochloric venereal infection at concentration of 2 mol dmAs you can see the hydrochloric corrosive is likewise concentrated for titration (i.e. one drop could switch over the colour of the solution.) therefore this biting entrust affect to be diluted.Background k noledgeLimewater can be made by dissolved slacked lime in water to get a solution of calcium hydroxide (Ca (OH) 2 )Quicklime + water slaked limeCaO (s) + H2O (l) CaCl2 (aq) + 2H2O (l)In this reaction it shows the calcium oxide reacts with water to produce calcium hydroxide. After adding more water to calcium hydroxide, it produces the saturated aqueous solution k straightawayn as limewater.My experiment will be base on this neutralisation reaction between the limewater and hydrochloric acid.Ca(OH) 2(aq) + HCl (aq) CaCl2 (aq) + 2H2O (l)back ground knowledge of limewater provided by AS chemical science 1 pageDiluting hydrochloric acidMy commencement task for this experiment is to dilute the hydrochloric acid. To do this I first needed to work out how m whatever groins I wished for hydrochloric acid. For this part of my calculation I conduct to use text book Calculations for chemistry to help me. Page..Ca(OH) 2(aq) + HCl (aq) CaCl2 (aq) + 2H2O (l)1gdm of Ca(OH) 2Number of moles of limewaterMr of lime water= 40.1 + (16 x 2) + (1 x 2) = 74.1Mass of lime water=1gMoles of lime water =mass(g)/MrSo 1/74.1=0.13 mol dm-3Molarities of limewater solutionMorality = no. moles of limewater / volume= 0.013 / 1 = 0.013 mol dmSo there is 0.013 mole of Ca(OH) 2 per every 1000cm3 of solution.Therefore 25cm should contain 3.2510-4 moles of Ca(OH) 2.0.013/40=3.2510-4 moleRatio of limewater Hydrochloric acid = 1 2= 3.25 x 10 6.5 x 10The hydrochloric acid is 2M which is 2 moles HCl in 1dm of solution.I need 6.5 x 10 moles of acid. Now I need to work out the volume of hydrochloric acid like this tawdriness = no. moles x 1000 / concentration = 6.5 x 10 x 1000 / 2 = 0.325cmI want a 25cm titre that contains 6.5 x 10 mol dmNow I need to work out the concentration of hydrochloric acid.Concentration = no. moles x 1000 / volume = 6.5 x 10 x 1000 / 25 = 0.026 mol dmI now know that I want 0.026-mol dm of hydrochloric acid for the reaction to work. But I have been supplied with 2.00-mol solution. I want 250cm of dilute hydrochloric acid at 0.026-mol dm. The total no. moles in 250cm is unknown. 250 cm of the solution should be enough to repeat the experiment. rack up number of moles of HCLNo. moles = concentration x volume / 1000This equation is rearranged to make masses = no. moles x 1000 / concentrationSo 1000cm contains 0.026 moles therefore 250cm contains 0.0065 molesVolume of hydrochloric acid I need Volume = no. moles x 1000 / concentration = 0. 0065 x 1000 / 2 =3.25cmApparatusPipette25mlBurette50mlConical flask 250cmVolumetric flask 250cmGraduated pipetteClamp + standWhite paperDistilled water power play pumpSafetyConcentrated HCL moldiness be handled with extreme caution due to its corrosive property. gawp and lab coat must be worn all the way through the experiment.Rubber gloves must be worn when handling concentrated HCL.Hazard sheet must be filled in front the experiment.Chemicals used for my titrationChemical in burette hydrochloric acid( 0.026mol dm )Chemical in conical flask lime waterIndicator methyl radical orangeMethodHere is how I am going to feed out my experimentPart 1 diluting acid. come the 3.25cm of hydrochloric acid to the volumetric flask using the receive pipette to get the exact amount of hydrochloric acid.Fill the same volumetric flask with distilled water until is reaches 250ml. This should now make my dilute hydrochloric acid with 0.0065 -mol dm. Now the hydrochloric acid is ready.Part 2 the tit ration.Wash burette with tip off water, then distilled water and at long last with hydrochloric acid.Wash the conical flask with tap water, then distilled water and finally with limewaterSet up titration apparatus.Fill the burette with 50cm of the dilute hydrochloric acid reservation sure the bottom of the semilunar cartilage is reading at 50 on the burette. Using a funnel to put the dilute hydrochloric acid in the burette increases safety against spillage.Fill the conical flask with 25cm of limewater using the squeezing pump and pipette.Add three drops of methyl orange to the limewater and mix until it turns a light yellow depending on the concentration of the methyl orange.Place the conical flask containing limewater onto a white paper.Start to run the dilute hydrochloric acid steadily, kickoff of constantly when a you see a localised colour change, then start to add little drops, finally into drop by drop. shake the conical flask after every drop of HCL is added. This will make sure you will use the exact amount of hydrochloric acid when the colour changes. This improves accuracy and reliability. assume all the tests at least three times (Time dependent) so that an average can be obtained. repetition the experiments several times will help to produce better and more accurate results, as any inaccuracies in one experiment should be compensated for by the other experiments. Note all the results in a table.One thing I have to decide is what indicator I want to use. The indicators methyl orange and phenolphthalein are pretty much one-three drops change and a clear change. The pink/colourless change for phenolphthalein is very definite, the yellow/pink change for methyl orange is clear too. Because these are clear it way of life I can tell when the reaction has finished easier than using other indicators. Limewater, which is calcium hydroxide, is a impregnable alkali, til now though it is yet sparing soluble. Its pH is 14. Hydrochloric acid is a stron g acid. This means that even if you have quite a weak concentration it completely dissociates in water into H3O+ ions and OH- ions giving a pH of 1 (The pH is a measure of how many hydrogen ions are present in solution).For the reaction of Calcium hydroxide and Hydrochloric acid I would use methyl orange. It changes colour at nigh pH 4.4 and will change from yellow in acid to pink in alkali by the addition of limewater. To make this experiment as accurate as possible, the pipette, burette and volumetric flask only have a percentage error of + or 0.1%. This is only a small error. Also making sure the hydrochloric acid is poured into the burette carefully using a funnel will prevent the hydrochloric acid pouring down the side of the burette.